Polarization

Polaroid sunglasses are familiar to most of us. They have a special ability to cut the glare of light reflected from water or glass ( see [Figure 1]). Polaroids have this ability because of a wave characteristic of light called polarization. What is polarization? How is it produced? What are some of its uses? The answers to these questions are related to the wave character of light.

Two photographs side by side of the same calm stream bed. In photograph a, the reflections of the clouds and some blue sky prevent you from seeing the pebbles in the streambed. In photograph b, there is essentially no reflection of the sky from the water’s surface, and the pebbles underneath the water are clearly visible.

Light is one type of electromagnetic (EM) wave. As noted earlier, EM waves are transverse waves consisting of varying electric and magnetic fields that oscillate perpendicular to the direction of propagation ( see [Figure 2]). There are specific directions for the oscillations of the electric and magnetic fields. Polarization is the attribute that a wave’s oscillations have a definite direction relative to the direction of propagation of the wave. (This is not the same type of polarization as that discussed for the separation of charges.) Waves having such a direction are said to be polarized. For an EM wave, we define the direction of polarization to be the direction parallel to the electric field. Thus we can think of the electric field arrows as showing the direction of polarization, as in [Figure 2].

The schematic shows an axis labeled c that points to the right. On this axis are two sinusoidal waves that are in phase. The wave labeled E oscillates up down in the vertical plane and the wave labeled B oscillates back and forth in the horizontal plane. At the tip of the axis c is a double headed arrow oriented vertically that is labeled direction of polarization.

To examine this further, consider the transverse waves in the ropes shown in [Figure 3]. The oscillations in one rope are in a vertical plane and are said to be vertically polarized. Those in the other rope are in a horizontal plane and are horizontally polarized. If a vertical slit is placed on the first rope, the waves pass through. However, a vertical slit blocks the horizontally polarized waves. For EM waves, the direction of the electric field is analogous to the disturbances on the ropes.

The figure shows waves on a vertically oscillating rope that pass through a vertical slit. A separate drawing shows waves on a horizontally oscillating rope that do not pass through a similar slit.

The Sun and many other light sources produce waves that are randomly polarized ( see [Figure 4]). Such light is said to be unpolarized because it is composed of many waves with all possible directions of polarization. Polaroid materials, invented by the founder of Polaroid Corporation, Edwin Land, act as a polarizing slit for light, allowing only polarization in one direction to pass through. Polarizing filters are composed of long molecules aligned in one direction. Thinking of the molecules as many slits, analogous to those for the oscillating ropes, we can understand why only light with a specific polarization can get through. The axis of a polarizing filter is the direction along which the filter passes the electric field of an EM wave ( see [Figure 5]).

The figure shows a slender arrow pointing out of the page and to the right; it is labeled direction of ray (of propagation). At a point on this ray, eight bold arrows point in different directions, perpendicularly away from the ray. These arrows are labeled E.

The figure shows a slender arrow pointing out of the page and to the right that is labeled direction of ray. At the left end of the ray are eight blue arrows emanating from a point on the ray. These arrows are all in a plane perpendicular to the ray and are symmetrically oriented in the perpendicular plane. They are labeled E. Farther to the right on the same ray is a thin rectangle labeled polarizing filter that is in the plane perpendicular to the ray. This filter has seven vertical lines that are equally spaced on its surface. It also has a vertical double headed arrow on its surface that is labeled axis. Still farther along the ray is a single blue double headed arrow oriented vertically that is labeled E and direction of polarization.

[Figure 6] shows the effect of two polarizing filters on originally unpolarized light. The first filter polarizes the light along its axis. When the axes of the first and second filters are aligned (parallel), then all of the polarized light passed by the first filter is also passed by the second. If the second polarizing filter is rotated, only the component of the light parallel to the second filter’s axis is passed. When the axes are perpendicular, no light is passed by the second.

Only the component of the EM wave parallel to the axis of a filter is passed. Let us call the angle between the direction of polarization and the axis of a filter $\theta$ . If the electric field has an amplitude $E$ , then the transmitted part of the wave has an amplitude $E \cos \theta$ (see [Figure 7]). Since the intensity of a wave is proportional to its amplitude squared, the intensity $I$ of the transmitted wave is related to the incident wave by

$$I={I}_{0} {\cos}^{2} \theta \text{,} $$

where ${I}_{0}$ is the intensity of the polarized wave before passing through the filter. (The above equation is known as Malus’s law.)

This figure has four subfigures. The first three are schematics and the last is a photograph. The first schematic looks much as in the previous figure, except that there is a second polarizing filter on the axis after the first one. The second polarizing filter has its lines aligned parallel to those of the first polarizing filter (i e, vertical). The vertical double headed arrow labeled E that emerges from the first polarizing filter also passes through the second polarizing filter. The next schematic is similar to the first, except that the second polarizing filter is rotated at forty five degrees with respect to the first polarizing filter. The double headed arrow that emerges from this second filter is also oriented at this same angle. It is also noticeably shorter than the other double headed arrows. The third schematic shows the same situation again, except that the second polarizing filter is now rotated ninety degrees with respect to the first polarizing filter. This time, there is no double headed arrow at all after the second polarizing filter. Finally, the last subfigure shows a photo of three circular optical filters placed over a bright colorful pattern. Two of these filters are place next to each other and the third is placed on top of the other two so that the center of the third is at the point where the edges of the two filters underneath touch. Some light passes through where the upper filter overlaps the left-hand underneath filter. Where the upper filter overlaps the right-hand lower filter, no light passes through.

This schematic is another variation of the schematic first introduced two figures prior. To the left of the vertically oriented polarizing filter is a double headed blue arrow oriented in the plane perpendicular to the propagation direction and at an angle theta with the vertical. After the polarizing filter a smaller vertical double headed arrow appears, which is labeled E cosine theta.

Calculating Intensity Reduction by a Polarizing Filter

What angle is needed between the direction of polarized light and the axis of a polarizing filter to reduce its intensity by $90.0%$ ?

Strategy

When the intensity is reduced by $90.0\%$ , it is $10.0\%$ or 0.100 times its original value. That is, $I= 0.100{I}_{0}$ . Using this information, the equation $I={I}_{0} {\cos}^{2} \theta$ can be used to solve for the needed angle.

Solution

Solving the equation $I={I}_{0} {\cos}^{2} \theta$ for $\cos \theta$ and substituting with the relationship between $I$ and ${I}_{0}$ gives

$$\cos \theta =\sqrt{\frac{I}{ {I}_{0}}}=\sqrt{\frac{ 0.100{I}_{0}}{ {I}_{0}}}=0.3162 \text{.} $$

Solving for $\theta$ yields

$$\theta ={\cos}^{-1 } 0.3162= 71.6º. $$

Discussion

A fairly large angle between the direction of polarization and the filter axis is needed to reduce the intensity to $10.0\%$ of its original value. This seems reasonable based on experimenting with polarizing films. It is interesting that, at an angle of $45 ^\circ$ , the intensity is reduced to $50 \%$ of its original value (as you will show in this section’s Problems & Exercises). Note that $71.6º$ is $18.4º$ from reducing the intensity to zero, and that at an angle of $18.4º$ the intensity is reduced to $90.0%$ of its original value (as you will also show in Problems & Exercises), giving evidence of symmetry.

Polarization by Reflection

By now you can probably guess that Polaroid sunglasses cut the glare in reflected light because that light is polarized. You can check this for yourself by holding Polaroid sunglasses in front of you and rotating them while looking at light reflected from water or glass. As you rotate the sunglasses, you will notice the light gets bright and dim, but not completely black. This implies the reflected light is partially polarized and cannot be completely blocked by a polarizing filter.

[Figure 8] illustrates what happens when unpolarized light is reflected from a surface. Vertically polarized light is preferentially refracted at the surface, so that the reflected light is left more horizontally polarized. The reasons for this phenomenon are beyond the scope of this text, but a convenient mnemonic for remembering this is to imagine the polarization direction to be like an arrow. Vertical polarization would be like an arrow perpendicular to the surface and would be more likely to stick and not be reflected. Horizontal polarization is like an arrow bouncing on its side and would be more likely to be reflected. Sunglasses with vertical axes would then block more reflected light than unpolarized light from other sources.

The schematic shows a block of glass in air. A ray labeled unpolarized light starts at the upper left and impinges on the center of the block. Centered on this ray is a symmetric star burst pattern of double headed arrows. From this point where this ray hits the glass block there emerges a reflected ray that goes up and to the right and a refracted ray that goes down and to the right. Both of these rays are labeled partially polarized light. The reflected ray has evenly spaced large black dots on it that are labeled perpendicular to plane of paper. Centered on each black dot is a double headed arrow that is rather short and is perpendicular to the ray. The refracted ray also has evenly spaced dots, but they are much smaller. Centered on each of these small black dots are quite large doubled headed arrows that are perpendicular to the refracted ray.

Since the part of the light that is not reflected is refracted, the amount of polarization depends on the indices of refraction of the media involved. It can be shown that reflected light is completely polarized at a angle of reflection ${\theta }_{\text{b}}$ , given by

$$\tan {\theta }_{\text{b}}=\frac{ {n}_{2}}{ {n}_{1}}\text{,} $$

where ${n}_{1}$ is the medium in which the incident and reflected light travel and ${n}_{2}$ is the index of refraction of the medium that forms the interface that reflects the light. This equation is known as Brewster’s law, and ${\theta }_{\text{b}}$ is known as Brewster’s angle, named after the 19th-century Scottish physicist who discovered them.

Things Great and Small: Atomic Explanation of Polarizing Filters

Polarizing filters have a polarization axis that acts as a slit. This slit passes electromagnetic waves (often visible light) that have an electric field parallel to the axis. This is accomplished with long molecules aligned perpendicular to the axis as shown in [Figure 8].

The schematic shows a stack of long identical horizontal molecules. A vertical axis is drawn over the molecules.

[Figure 10] illustrates how the component of the electric field parallel to the long molecules is absorbed. An electromagnetic wave is composed of oscillating electric and magnetic fields. The electric field is strong compared with the magnetic field and is more effective in exerting force on charges in the molecules. The most affected charged particles are the electrons in the molecules, since electron masses are small. If the electron is forced to oscillate, it can absorb energy from the EM wave. This reduces the fields in the wave and, hence, reduces its intensity. In long molecules, electrons can more easily oscillate parallel to the molecule than in the perpendicular direction. The electrons are bound to the molecule and are more restricted in their movement perpendicular to the molecule. Thus, the electrons can absorb EM waves that have a component of their electric field parallel to the molecule. The electrons are much less responsive to electric fields perpendicular to the molecule and will allow those fields to pass. Thus the axis of the polarizing filter is perpendicular to the length of the molecule.

The figure contains two schematics. The first schematic shows a long molecule. An EM wave goes through the molecule. The ray of the EM wave is at ninety degrees to the molecular axis and the electric field of the EM wave oscillates along the molecular axis. After passing the long molecule, the magnitude of the oscillations of the EM wave are significantly reduced. The second schematic shows a similar drawing, except that the EM wave oscillates perpendicular to the axis of the long molecule. After passing the long molecule, the magnitude of the oscillation of the EM wave is unchanged.

Calculating Polarization by Reflection

(a) At what angle will light traveling in air be completely polarized horizontally when reflected from water? (b) From glass?

Strategy

All we need to solve these problems are the indices of refraction. Air has ${n}_{1}=1.00,$ water has ${n}_{2}=1.333\text{,}$ and crown glass has $n^{\prime}_{2}=1.520$ . The equation $\tan {\theta }_{\text{b}}=\frac{ {n}_{2}}{ {n}_{1}}$ can be directly applied to find ${\theta }_{\text{b}}$ in each case.

Solution for (a)

Putting the known quantities into the equation

$$\tan {\theta }_{\text{b}}=\frac{ {n}_{2}}{ {n}_{1}} $$

gives

$$\tan {\theta }_{\text{b}}=\frac{ {n}_{2}}{ {n}_{1}}=\frac{1.333}{1.00}=1.333 \text{.} $$

Solving for the angle ${\theta }_{\text{b}}$ yields

$${\theta }_{\text{b}}={\tan}^{-1} 1.333= 53.1º. $$

Solution for (b)

Similarly, for crown glass and air,

$${\tan \theta^{\prime} }_{\text{b}}=\frac{ n^{\prime}_{2}}{ {n}_{1}}=\frac{1.520}{1.00}=1.52 \text{.} $$

Thus,

$${\theta^{\prime} }_{\text{b}}={\tan}^{-1 } 1.52=56.7 \text{º.} $$

Discussion

Light reflected at these angles could be completely blocked by a good polarizing filter held with its axis vertical. Brewster’s angle for water and air are similar to those for glass and air, so that sunglasses are equally effective for light reflected from either water or glass under similar circumstances. Light not reflected is refracted into these media. So at an incident angle equal to Brewster’s angle, the refracted light will be slightly polarized vertically. It will not be completely polarized vertically, because only a small fraction of the incident light is reflected, and so a significant amount of horizontally polarized light is refracted.

Polarization by Scattering

If you hold your Polaroid sunglasses in front of you and rotate them while looking at blue sky, you will see the sky get bright and dim. This is a clear indication that light scattered by air is partially polarized. [Figure 10] helps illustrate how this happens. Since light is a transverse EM wave, it vibrates the electrons of air molecules perpendicular to the direction it is traveling. The electrons then radiate like small antennae. Since they are oscillating perpendicular to the direction of the light ray, they produce EM radiation that is polarized perpendicular to the direction of the ray. When viewing the light along a line perpendicular to the original ray, as in [Figure 11], there can be no polarization in the scattered light parallel to the original ray, because that would require the original ray to be a longitudinal wave. Along other directions, a component of the other polarization can be projected along the line of sight, and the scattered light will only be partially polarized. Furthermore, multiple scattering can bring light to your eyes from other directions and can contain different polarizations.

The schematic shows a ray labeled unpolarized sunlight coming horizontally from the left along what we shall call the x axis. On this ray is a symmetric star burst pattern of double headed arrows, with all the arrows in the plane perpendicular to the ray, This ray strikes a dot labeled molecule. From the molecule three rays emerge. One ray goes straight down, in the negative y direction. It is labeled polarized light and has a single double headed arrow on it that is perpendicular to the plane of the page, that is, the double headed arrow is parallel to the z axis. A second ray continues from the molecule in the same direction as the incoming ray and is labeled unpolarized light. This ray also has a symmetric star burst pattern of double headed arrows on it. A final ray comes out of the plane of the paper in the x z plane, at about 45 degrees from the x axis. This ray is labeled partially polarized light and has a nonsymmetric star burst pattern of double headed arrows on it.

Photographs of the sky can be darkened by polarizing filters, a trick used by many photographers to make clouds brighter by contrast. Scattering from other particles, such as smoke or dust, can also polarize light. Detecting polarization in scattered EM waves can be a useful analytical tool in determining the scattering source.

There is a range of optical effects used in sunglasses. Besides being Polaroid, other sunglasses have colored pigments embedded in them, while others use non-reflective or even reflective coatings. A recent development is photochromic lenses, which darken in the sunlight and become clear indoors. Photochromic lenses are embedded with organic microcrystalline molecules that change their properties when exposed to UV in sunlight, but become clear in artificial lighting with no UV.

Take-Home Experiment: Polarization

Find Polaroid sunglasses and rotate one while holding the other still and look at different surfaces and objects. Explain your observations. What is the difference in angle from when you see a maximum intensity to when you see a minimum intensity? Find a reflective glass surface and do the same. At what angle does the glass need to be oriented to give minimum glare?

Liquid Crystals and Other Polarization Effects in Materials

While you are undoubtedly aware of liquid crystal displays (LCDs) found in watches, calculators, computer screens, cellphones, flat screen televisions, and other myriad places, you may not be aware that they are based on polarization. Liquid crystals are so named because their molecules can be aligned even though they are in a liquid. Liquid crystals have the property that they can rotate the polarization of light passing through them by $90 ^\circ$ . Furthermore, this property can be turned off by the application of a voltage, as illustrated in [Figure 12]. It is possible to manipulate this characteristic quickly and in small well-defined regions to create the contrast patterns we see in so many LCD devices.

In flat screen LCD televisions, there is a large light at the back of the TV. The light travels to the front screen through millions of tiny units called pixels (picture elements). One of these is shown in [Figure 12] (a) and (b). Each unit has three cells, with red, blue, or green filters, each controlled independently. When the voltage across a liquid crystal is switched off, the liquid crystal passes the light through the particular filter. One can vary the picture contrast by varying the strength of the voltage applied to the liquid crystal.

The figure contains two schematics and one photograph. The first schematic shows a ray of initially unpolarized light going through a vertical polarizer, then an element labeled L C D no voltage ninety degree rotation, then finally a horizontal polarizer. The initially unpolarized light becomes vertically polarized after the vertical polarizer, then is rotated ninety degrees by the L C D element so that it is horizontally polarized, then it passes through the horizontal polarizer. The second schematic is the same except that the L C D element is labeled voltage on, no rotation. The light coming out of the L C D element is thus vertically polarized and does not pass through the horizontal polarizer. Finally, a photograph is shown of a laptop computer that is open so that you can see its screen, which is on and has some icons and windows visible.

Many crystals and solutions rotate the plane of polarization of light passing through them. Such substances are said to be optically active. Examples include sugar water, insulin, and collagen (see [Figure 12]). In addition to depending on the type of substance, the amount and direction of rotation depends on a number of factors. Among these is the concentration of the substance, the distance the light travels through it, and the wavelength of light. Optical activity is due to the asymmetric shape of molecules in the substance, such as being helical. Measurements of the rotation of polarized light passing through substances can thus be used to measure concentrations, a standard technique for sugars. It can also give information on the shapes of molecules, such as proteins, and factors that affect their shapes, such as temperature and pH.

The schematic shows an initially unpolarized ray of light that passes through three optical elements. The first is a vertical polarizer, so the electric field is vertical after the ray passes through it. Next comes a block that is labeled optically active. Following this block the electric field has been rotated by an angle theta with respect to the vertical. In the schematic this angle is about forty five degrees. Finally, the ray passes through another vertical polarizer that is labeled analyzer. A shorter and vertically oriented electric field appears after this element.

Glass and plastic become optically active when stressed; the greater the stress, the greater the effect. Optical stress analysis on complicated shapes can be performed by making plastic models of them and observing them through crossed filters, as seen in [Figure 14]. It is apparent that the effect depends on wavelength as well as stress. The wavelength dependence is sometimes also used for artistic purposes.

The figure shows a photograph of a transparent circular plastic lens that is being pinched between clamp fingers. The lens is deformed and rainbows of colors are visible whose outlines roughly follow the deformation of the object.

Another interesting phenomenon associated with polarized light is the ability of some crystals to split an unpolarized beam of light into two. Such crystals are said to be birefringent (see [Figure 15]). Each of the separated rays has a specific polarization. One behaves normally and is called the ordinary ray, whereas the other does not obey Snell’s law and is called the extraordinary ray. Birefringent crystals can be used to produce polarized beams from unpolarized light. Some birefringent materials preferentially absorb one of the polarizations. These materials are called dichroic and can produce polarization by this preferential absorption. This is fundamentally how polarizing filters and other polarizers work. The interested reader is invited to further pursue the numerous properties of materials related to polarization.

The schematic shows an unpolarized ray of light incident on a block of transparent material The ray is perpendicular to the face of the material. Upon entering the material, part of the ray continues straight on. This ray is horizontally polarized and is labeled o. Another part of the incident ray is deviated at an angle upon entering the material. This ray is vertically polarized and is labeled e.

Section Summary

Conceptual Questions

Under what circumstances is the phase of light changed by reflection? Is the phase related to polarization?

Can a sound wave in air be polarized? Explain.

No light passes through two perfect polarizing filters with perpendicular axes. However, if a third polarizing filter is placed between the original two, some light can pass. Why is this? Under what circumstances does most of the light pass?

Explain what happens to the energy carried by light that it is dimmed by passing it through two crossed polarizing filters.

When particles scattering light are much smaller than its wavelength, the amount of scattering is proportional to $1/{\lambda }^{4}$ . Does this mean there is more scattering for small $\lambda$ than large $\lambda$ ? How does this relate to the fact that the sky is blue?

Using the information given in the preceding question, explain why sunsets are red.

When light is reflected at Brewster’s angle from a smooth surface, it is $100 \%$ polarized parallel to the surface. Part of the light will be refracted into the surface. Describe how you would do an experiment to determine the polarization of the refracted light. What direction would you expect the polarization to have and would you expect it to be $100 \%$ ?

Problems & Exercises

What angle is needed between the direction of polarized light and the axis of a polarizing filter to cut its intensity in half?

Strategy

Use Malus’s law: $I = I_0 \cos^2 \theta$. For the intensity to be cut in half, I = I₀/2.

Solution

Setting I = I₀/2:

$$\frac{I_0}{2} = I_0 \cos^2 \theta$$
$$\cos^2 \theta = \frac{1}{2} = 0.500$$
$$\cos \theta = \sqrt{0.500} = 0.7071$$
$$\theta = \cos^{-1}(0.7071) = 45.0°$$

Discussion

The 45° angle is exactly halfway between parallel (0°, maximum transmission) and perpendicular (90°, zero transmission). This symmetric position naturally corresponds to 50% transmission. This relationship is important in many optical applications, including variable neutral density filters and light intensity modulators where precise control over light intensity is needed.

The angle between the axes of two polarizing filters is $45.0º$ . By how much does the second filter reduce the intensity of the light coming through the first?

Strategy

Use Malus’s law: $I = I_0 \cos^2 \theta$ where θ = 45.0° is the angle between the polarizer axes.

Solution

After passing through the first polarizing filter, the light is fully polarized with intensity I₀. When this polarized light passes through the second filter at angle θ = 45.0°:

$$I = I_0 \cos^2 \theta = I_0 \cos^2 45.0°$$
$$I = I_0 (0.7071)^2 = I_0 (0.500) = 0.500 I_0$$

The second filter reduces the intensity to 50.0% of the value after the first filter, which means it reduces the intensity by 50.0% (or cuts it in half).

Discussion

This 50% reduction at 45° is a special case. At θ = 0° (parallel axes), no reduction occurs (I = I₀). At θ = 90° (perpendicular axes), complete extinction occurs (I = 0). The 45° angle represents the midpoint where exactly half the intensity passes through. This property is used in variable neutral density filters and light modulators.

If you have completely polarized light of intensity $150 \text{W}/{\text{m}}^{2}$ , what will its intensity be after passing through a polarizing filter with its axis at an $89.0º$ angle to the light’s polarization direction?

Strategy

Use Malus’s law: $I = I_0 \cos^2 \theta$ with I₀ = 150 W/m² and θ = 89.0°.

Solution

$$I = I_0 \cos^2 \theta = (150 \text{ W/m}^2) \cos^2 89.0°$$
$$I = (150) (0.01746)^2 = (150)(3.048 \times 10^{-4})$$
$$I = 0.0457 \text{ W/m}^2 = 45.7 \text{ mW/m}^2$$

Discussion

At 89.0°, the filter axis is nearly perpendicular to the polarization direction (only 1° from complete extinction). The transmitted intensity is reduced to about 0.03% of the original—a dramatic reduction. This demonstrates how sensitive polarization effects are near 90°. Just one degree away from perpendicular allows a small but measurable amount of light to pass through.

What angle would the axis of a polarizing filter need to make with the direction of polarized light of intensity $1.00 {\text{kW/m}}^{2}$ to reduce the intensity to $10.0 {\text{W/m}}^{2}$ ?

Strategy

Use Malus’s law $I = I_0 \cos^2 \theta$ and solve for θ.

Solution

Given: I₀ = 1.00 kW/m² = 1000 W/m², I = 10.0 W/m²

$$I = I_0 \cos^2 \theta$$
$$\cos \theta = \sqrt{\frac{I}{I_0}} = \sqrt{\frac{10.0}{1000}} = \sqrt{0.0100} = 0.100$$
$$\theta = \cos^{-1}(0.100) = 84.3°$$

Discussion

The angle of 84.3° is close to 90° (perpendicular), which makes sense for such a large intensity reduction (to 1% of original). This is just 5.7° away from complete extinction.

At the end of [Example 1], it was stated that the intensity of polarized light is reduced to $90.0%$ of its original value by passing through a polarizing filter with its axis at an angle of $18.4º$ to the direction of polarization. Verify this statement.

Strategy

Use Malus’s law: $I = I_0 \cos^2 \theta$ with θ = 18.4° and verify that I/I₀ = 0.900.

Solution

$$I = I_0 \cos^2 18.4° = I_0 (0.9483)^2$$
$$I = I_0 (0.8993) \approx 0.900 I_0$$

Therefore, $I = 90.0\% \text{ of } I_0$, which verifies the statement.

Discussion

This confirms the symmetric relationship mentioned in Example 1: at 18.4° from the polarization direction, the intensity is reduced to 90% (meaning 10% is blocked). At 71.6° (which is 18.4° from perpendicular), the intensity is reduced to 10% (meaning 90% is blocked). These complementary angles (18.4° + 71.6° = 90°) demonstrate the symmetry of the cosine-squared function in Malus’s law.

Show that if you have three polarizing filters, with the second at an angle of $45 ^\circ$ to the first and the third at an angle of $90.0º$ to the first, the intensity of light passed by the first will be reduced to $25.0%$ of its value. (This is in contrast to having only the first and third, which reduces the intensity to zero, so that placing the second between them increases the intensity of the transmitted light.)

Strategy

Apply Malus’s law twice: once for the first-to-second filter (θ = 45°), then for the second-to-third filter (θ = 45° also, since third is 90° from first).

Solution

Let I₀ be the intensity after the first polarizer.

After second filter (45° from first):

$$I_2 = I_0 \cos^2 45° = I_0 (0.7071)^2 = 0.500 I_0$$

After third filter (90° from first, so 45° from second):

$$I_3 = I_2 \cos^2 45° = (0.500 I_0)(0.500) = 0.250 I_0$$

Therefore, the final intensity is 25.0% of I₀. Q.E.D.

Discussion

With only the first and third filters (at 90°), I = I₀ cos²(90°) = 0 (no light passes). But inserting a 45° filter between them allows 25% transmission! This counterintuitive result occurs because the middle filter “rotates” the polarization direction, allowing some light to pass through the final filter.

Prove that, if $I$ is the intensity of light transmitted by two polarizing filters with axes at an angle $\theta$ and $I^{\prime}$ is the intensity when the axes are at an angle $90.0 ^\circ-\theta ,$ then $I+I^{\prime}={I}_{0,}$ the original intensity. (Hint: Use the trigonometric identities $\cos \left(90.0º-\theta \right)=\sin \theta$ and ${\cos}^{2} \theta +{\sin}^{2} \theta =1.$ )

Strategy

Apply Malus’s law to both angle configurations and use the given trigonometric identities to show the intensities sum to I₀.

Solution

For the first configuration at angle θ:

$$I = I_0 \cos^2 \theta$$

For the second configuration at angle (90° - θ):

$$I' = I_0 \cos^2(90° - \theta)$$

Using the identity $\cos(90° - \theta) = \sin \theta$:

$$I' = I_0 \sin^2 \theta$$

Now add the two intensities:

$$I + I' = I_0 \cos^2 \theta + I_0 \sin^2 \theta$$
$$I + I' = I_0 (\cos^2 \theta + \sin^2 \theta)$$

Using the fundamental identity $\cos^2 \theta + \sin^2 \theta = 1$:

$$I + I' = I_0 (1) = I_0$$

Therefore: $I + I' = I_0$ Q.E.D.

Discussion

This beautiful result shows that complementary polarizer angles transmit intensities that sum to the original intensity. For example, if a 30° filter transmits 75% of the light, then a 60° filter (90° - 30°) transmits the remaining 25%. This conservation of energy makes physical sense: the total transmitted light through the two complementary orientations equals what would pass if there were no angular selectivity at all.

At what angle will light reflected from diamond be completely polarized?

Strategy

Use Brewster’s law: $\tan \theta_b = n_2/n_1$ where n₁ = 1.00 (air) and n₂ = 2.419 (diamond).

Solution

$$\tan \theta_b = \frac{2.419}{1.00} = 2.419$$
$$\theta_b = \tan^{-1}(2.419) = 67.5°$$

Discussion

Diamond’s high refractive index (2.419) produces a large Brewster angle of 67.5°, close to grazing incidence. This is why diamonds sparkle brilliantly - their high index causes strong refraction and internal reflection at most angles.

What is Brewster’s angle for light traveling in water that is reflected from crown glass?

Strategy

Use Brewster’s law: $\tan \theta_b = n_2/n_1$ where n₁ = 1.333 (water) and n₂ = 1.52 (crown glass).

Solution

$$\tan \theta_b = \frac{n_2}{n_1} = \frac{1.52}{1.333} = 1.140$$
$$\theta_b = \tan^{-1}(1.140) = 48.8°$$

Discussion

Brewster’s angle of 48.8° applies when light travels through water and reflects off crown glass (such as the glass wall of an aquarium). This is smaller than Brewster’s angle for air-to-glass reflection (56.7°) because the difference in refractive indices is smaller when starting from water (n = 1.333) rather than air (n = 1.00). The smaller index contrast means the reflected light becomes completely polarized at a smaller angle from the normal.

A scuba diver sees light reflected from the water’s surface. At what angle will this light be completely polarized?

Strategy

The diver is underwater looking up at the water-air interface. Use Brewster’s law with n₁ = 1.33 (water) and n₂ = 1.00 (air).

Solution

$$\tan \theta_b = \frac{n_2}{n_1} = \frac{1.00}{1.33} = 0.752$$
$$\theta_b = \tan^{-1}(0.752) = 36.9°$$

Discussion

The Brewster angle of 36.9° from the normal (measured underwater) is relatively small. This is the complement of the Brewster angle for light going from air to water (53.1°), since 36.9° + 53.1° = 90°.

At what angle is light inside crown glass completely polarized when reflected from water, as in a fish tank?

Strategy

Use Brewster’s law with light traveling in crown glass (n₁ = 1.52) and reflecting from water (n₂ = 1.333).

Solution

$$\tan \theta_b = \frac{n_2}{n_1} = \frac{1.333}{1.52} = 0.8770$$
$$\theta_b = \tan^{-1}(0.8770) = 41.2°$$

Discussion

This is Brewster’s angle for light traveling inside the glass wall of a fish tank and reflecting off the water inside. Notice that this angle (41.2°) is the complement of the water-to-glass Brewster angle (48.8°), and indeed 41.2° + 48.8° = 90.0°, confirming the reciprocal relationship $\theta_b + \theta'_b = 90°$ for reflections from opposite sides of an interface. Light at this angle inside the glass would see complete polarization of the reflection from the water surface.

Light reflected at $55.6º$ from a window is completely polarized. What is the window’s index of refraction and the likely substance of which it is made?

Strategy

Since the light is completely polarized, θ = 55.6° is Brewster’s angle. Use $\tan \theta_b = n_2/n_1$ with n₁ = 1.00 (air).

Solution

$$n_2 = n_1 \tan \theta_b = (1.00) \tan 55.6° = 1.46$$

Discussion

An index of refraction of 1.46 is typical of window glass (common soda-lime glass has n ≈ 1.46-1.52). This could also be Plexiglas (n ≈ 1.49) or other transparent plastics used in windows.

(a) Light reflected at $62.5º$ from a gemstone in a ring is completely polarized. Can the gem be a diamond? (b) At what angle would the light be completely polarized if the gem was in water?

Strategy

For part (a), use Brewster’s law to find the index of refraction and compare to diamond (n = 2.419). For part (b), use the index found in (a) with water as the incident medium.

Solution

(a) Can the gem be a diamond?

Since the light is completely polarized, θ = 62.5° is Brewster’s angle. Using $\tan \theta_b = n_2/n_1$ with n₁ = 1.00 (air):

$$n_2 = n_1 \tan \theta_b = (1.00) \tan 62.5° = 1.92$$

Diamond has n = 2.419, which is significantly higher than 1.92. Therefore, this gem cannot be diamond.

The index of 1.92 is consistent with zircon (n ≈ 1.92-1.98) or cubic zirconia (n ≈ 2.15-2.18), which are common diamond simulants.

(b) Brewster’s angle if the gem is in water:

Using n₁ = 1.333 (water) and n₂ = 1.92 (from part a):

$$\tan \theta_b = \frac{n_2}{n_1} = \frac{1.92}{1.333} = 1.440$$
$$\theta_b = \tan^{-1}(1.440) = 55.2°$$

Discussion

The index of refraction is a definitive way to identify gemstones. Diamond’s exceptionally high index (2.419) would give a Brewster angle of 67.5°, much larger than the observed 62.5°. The calculated index of 1.92 rules out diamond and suggests zircon or a synthetic simulant. When the gem is immersed in water, Brewster’s angle decreases from 62.5° to 55.2° because the refractive index contrast is reduced.

If ${\theta }_{\text{b}}$ is Brewster’s angle for light reflected from the top of an interface between two substances, and ${\theta^{\prime} }_{\text{b}}$ is Brewster’s angle for light reflected from below, prove that ${\theta }_{\text{b}}+{\theta^{\prime} }_{\text{b}}= 90.0º.$

Strategy

Use Brewster’s law for both directions and the trigonometric identity $\tan \theta + \tan(90° - \theta) = \infty$ or $\tan \theta_1 \cdot \tan \theta_2 = 1$ when $\theta_1 + \theta_2 = 90°$.

Solution

For light from medium 1 (n₁) to medium 2 (n₂):

$$\tan \theta_b = \frac{n_2}{n_1}$$

For light from medium 2 to medium 1 (reverse direction):

$$\tan \theta'_b = \frac{n_1}{n_2}$$

Notice that:

$$\tan \theta_b \cdot \tan \theta'_b = \frac{n_2}{n_1} \cdot \frac{n_1}{n_2} = 1$$

From trigonometry, when $\tan \theta_b \cdot \tan \theta'_b = 1$, this occurs when $\theta_b + \theta'_b = 90°$ (since $\tan \theta \cdot \tan(90° - \theta) = \tan \theta \cdot \cot \theta = 1$).

Therefore: $\theta_b + \theta'_b = 90.0°$ Q.E.D.

Discussion

This complementary relationship means Brewster’s angles from opposite sides of an interface always sum to 90°. For example, air-to-water (θ_b ≈ 53°) and water-to-air (θ’_b ≈ 37°) sum to 90°.

Integrated Concepts

If a polarizing filter reduces the intensity of polarized light to $50.0\%$ of its original value, by how much are the electric and magnetic fields reduced?

Strategy

Intensity is proportional to the square of the electric field amplitude (and magnetic field amplitude). If I is reduced to 50%, find the reduction in E and B.

Solution

For electromagnetic waves, intensity is proportional to the square of the field amplitudes:

$$I \propto E^2 \propto B^2$$

If $I_2 = 0.500 I_1$, then:

$$\frac{I_2}{I_1} = \frac{E_2^2}{E_1^2} = 0.500$$
$$\frac{E_2}{E_1} = \sqrt{0.500} = 0.707$$

Therefore: $E_2 = 0.707 E_1$

Similarly: $B_2 = 0.707 B_1$

Both the electric and magnetic field amplitudes are reduced to 70.7% (or reduced by 29.3%) of their original values.

Discussion

The square-root relationship between field amplitude and intensity is fundamental to wave physics. When intensity drops by half, the fields don’t drop by half—they drop by a factor of √2 ≈ 0.707. This same relationship applies to all waves where intensity is proportional to amplitude squared, including sound waves and water waves.

Integrated Concepts

Suppose you put on two pairs of Polaroid sunglasses with their axes at an angle of $15.0º$ . How much longer will it take the light to deposit a given amount of energy in your eye compared with a single pair of sunglasses? Assume the lenses are clear except for their polarizing characteristics.

Strategy

Compare the intensity (power) transmitted through one vs. two pairs. Time to deposit energy is inversely proportional to power/intensity.

Solution

One pair: Unpolarized light through a polarizer transmits I₁ = I₀/2

Two pairs at 15°: First polarizer transmits I₀/2, then Malus’s law for the second:

$$I_2 = \frac{I_0}{2} \cos^2 15.0° = \frac{I_0}{2}(0.9659)^2 = 0.467 I_0$$

Time ratio (since Power = Energy/time):

$$\frac{t_2}{t_1} = \frac{I_1}{I_2} = \frac{0.500 I_0}{0.467 I_0} = 1.07$$

The two pairs take 7% longer (or equivalently, 1.07 times as long) to deposit the same energy.

Discussion

At only 15° misalignment, the second pair blocks relatively little additional light (cos²15° ≈ 0.93). The time difference is small. At 90° misalignment, no light would pass and it would take infinite time!

Integrated Concepts

(a) On a day when the intensity of sunlight is $1.00 \text{kW}/{\text{m}}^{2}$ , a circular lens 0.200 m in diameter focuses light onto water in a black beaker. Two polarizing sheets of plastic are placed in front of the lens with their axes at an angle of $20.0º.$ Assuming the sunlight is unpolarized and the polarizers are $100 \%$ efficient, what is the initial rate of heating of the water in $\text{ºC}/\text{s}$ , assuming it is $80.0\%$ absorbed? The aluminum beaker has a mass of 30.0 grams and contains 250 grams of water. (b) Do the polarizing filters get hot? Explain.

(a) $2.07 \times 10^{-2}$ ºC/s

(b) Yes, the polarizing filters get hot because they absorb some of the lost energy from the sunlight.

Glossary

axis of a polarizing filter
the direction along which the filter passes the electric field of an EM wave
birefringent
crystals that split an unpolarized beam of light into two beams
Brewster’s angle
${\theta }_{\text{b}}={\tan}^{-1}\left(\frac{ {n}_{2}}{ {n}_{1}}\right),$ where ${n}_{2}$ is the index of refraction of the medium from which the light is reflected and ${n}_{1}$ is the index of refraction of the medium in which the reflected light travels
Brewster’s law
$\tan {\theta }_{\text{b}}=\frac{ {n}_{2}}{ {n}_{1}}$ , where ${n}_{1}$ is the medium in which the incident and reflected light travel and ${n}_{2}$ is the index of refraction of the medium that forms the interface that reflects the light
direction of polarization
the direction parallel to the electric field for EM waves
horizontally polarized
the oscillations are in a horizontal plane
optically active
substances that rotate the plane of polarization of light passing through them
polarization
the attribute that wave oscillations have a definite direction relative to the direction of propagation of the wave
polarized
waves having the electric and magnetic field oscillations in a definite direction
reflected light that is completely polarized
light reflected at the angle of reflection ${\theta }_{\text{b}}$ , known as Brewster’s angle
unpolarized
waves that are randomly polarized
vertically polarized
the oscillations are in a vertical plane